Rovibrational transitions and nuclear spin conversion of methane in parahydrogen crystals
                    
                        
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منابع مشابه
Infrared spectroscopic study of rovibrational states of methane trapped in parahydrogen crystal
The n3 and n4 vibrational transitions of methane trapped in solid parahydrogen have been observed by using Fourier transform infrared and high resolution laser spectroscopy. The observed spectrum is interpreted in terms of rovibrational states of the spherical rotor which are subjected to the crystal field splitting. The n4 band shows extremely sharp lines of a width of ;0.003 cm , while the n3...
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Except for ortho- and para-H2, little is known about nuclear spin isomers (or spin modifications) of molecules. The main reason is the lack of practical enrichment techniques. Recently, a few enrichment methods were developed, which opened up new possibilities in the field. These methods are briefly reviewed. Substantial progress in the field has been made by the introduction of light-induced d...
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A theoretical model of hyperfine spectra of nuclear spin conversion of molecular isomers has been developed. The model takes into account the nuclear spin-spin and spin-rotation interactions, as well as the saturation of intramolecular mixing of molecular ortho and para states. The model has been applied to hyperfine spectra of nuclear spin conversion in CH3F molecules subjected to an external ...
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Nuclear level densities and spin cut-off factors have been deduced for nuclei in the mass region 24‹A‹63,from a microscopic theory, which includes nuclear pairing interaction. Single particle levels for both Seeger and Nilsson potentials were used in the calcdations. Level densities extracted from the theory are compared with their conesponding experimental values, It is found that the overall...
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The spin Peierls instability describes a structural transition of a crystal due to strong magnetic interactions. Here, we demonstrate that cold Coulomb crystals of trapped ions provide an experimental test bed in which to study this complex many-body problem and to access extreme regimes where the instability is triggered by quantum fluctuations alone. We present a consistent analysis based on ...
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ژورنال
عنوان ژورنال: Low Temperature Physics
سال: 2000
ISSN: 1063-777X,1090-6517
DOI: 10.1063/1.1312392